Effect of anisotropic transport properties of porous layers on the dynamic performance of proton exchange membrane fuel cell

Abstract

To study the influence of anisotropic transport properties of porous layers (PLs) on the dynamic performance (DP) of fuel cells (FC), a numerical model was developed. The model uses self-compiled codes to couple the actual structure of PLs with its transport capability, while introducing a non-homogeneous model that reflects the effect of the actual agglomerate structure of the catalyst layer on the electrochemical reaction, based on the consideration of the internal heat transport and external heat exchange of FC, the three-phase transformation of water, the change of momentum, energy, species, and water transport with time, and finally realizes the transient changes of complete transport and reaction process inside the FC. Using the current density as the input load, the law of the anisotropic transport properties of PLs on the FC's DP was explored. The results show that among all properties, the proton conductivity has the most significant influence on DP indexes such as steady-state transition time, over/undershoot amplitude, the electrical conductivity and diffusivity have similar and significant effects, the thermal conductivity and permeability have minor and most negligible effects, respectively. When designing the material, structure and composition of the PLs, the focus should be on protons, electron conductivity and diffusivity.