Abstract
Effect of supporting cations on the EDL structure is analyzed in the region of specific adsorption of anions. The analysis assumes that cations are pulled into the EDL dense part due to their interaction with specifically-adsorbed anions. The model describing this phenomenon is based on the introduction of a second, cationic IHP situated between the plane where centers of charges of specifically-adsorbed anions are localized and OHP. The adsorption of ions, electrode charge, PZC, and EDL capacitance are calculated using two adsorption isotherms for anions and cations.
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