Effect of an alternating current electric field on Co(OH)2 periodic precipitation

Abstract

The present paper studies the effect of an alternating current (AC) electric field on Co(OH)2 Liesegang patterns. In the presence of an AC electric field, the band spacing increases with spacing number, but reaches a plateau at large spacing (or band) numbers. The band spacing increases with applied AC voltage, but to a much lesser extent than the effect of a DC electric field under the same applied voltage [see R. Sultan, R. Halabieh, Chem. Phys. Lett. 332 (2000) 331][1]. At low enough applied voltage, the band spacing increases with frequency. At higher voltages, the band spacing becomes independent of the field frequency. The effect of concentration of the inner electrolyte (Co2+), exactly opposes that observed under DC electric field; i.e., the band spacing decreases with increasing concentration. The dynamics were shown to be governed by a competitive scenario between the diffusion gradient and the alternating current electric field factor.