Effect of amphiphilic block copolymers on the structure and phase behavior of oil–water-surfactant mixtures

Abstract

The effect of amphiphilic diblock copolymers of several molecular weights on the structure and phase behavior of ternary amphiphilic systems (water, oil, and nonionic surfactant) is investigated. Small amounts of amphiphilic block copolymer polyethyleneoxide–polyethylpropylene lead to a dramatic decrease of the amount of total surfactant needed to solubilize given equal volumes of water and oil in a bicontinuous microemulsion. Neutron scattering experiments employing a high-precision two-dimensional contrast variation technique demonstrate that the polymer is distributed uniformly on the surfactant membrane. Based on these observations, we propose a mechanism for the enhancement of swelling behavior, which is due to the variation of the membrane curvature elasticity by polymer mushrooms anchored to the interface.