Abstract

Aluminium pillared montmorillonites from Indonesian natural montmorillonite has been prepared using Al13 Keggin ion pillaring precursor in varied concentrations. Herein we studied their characterization and catalysis application for esterification reaction. X-ray diffraction (XRD), energy dispersive x-ray analysis (EDX), and BET gas sorption analysis were employed to characterize the prepared materials besides the characterization on surface acidity by pyridine and n-butylammine adsorptions and FTIR analysis. The result showed that significant improvement on physicochemical character data was obtained by a pillarization process. Such a process also provided improvements on catalytic activities in esterification reactions. The effect of aluminium content on material characters was discussed in this paper. It was observed from the catalytic activity tests that pillared montmorillonite samples demonstrated higher activity in esterification reaction relative to the raw montmorillonite. It was found that surface profile of materials consist of specific surface area, pore volume and Lewis acidity were significantly affect the catalyst activity.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.