Effect of aging temperature on the heterogeneous microstructure and mechanical properties of a 12Cr–10Ni–Mo–Ti maraging steel for cryogenic applications

Abstract

The evolution of heterogeneous microstructure and mechanical properties of a 12Cr–10Ni–Mo–Ti maraging steel was investigated at different aging temperatures. As the aging temperature increases, more reversed austenite forms with the recovery of martensite matrix. When aging temperature is up to 560 °C, more lath-like reversed austenite coalesces together and leads to the formation of martensite and austenite dual-phase microstructure. Fine η-Ni3(Ti, Al) particles initially precipitate at 440 °C and grow up with increased aging temperature. Notably, it was found that η-precipitates can be encompassed in reversed austenite at 500 °C. Thermodynamic calculations further verify the austenite reversion, and nanoprecipitation can occur independently of each other though there is competition of Ni element. However, it leads to the coarsening and dissolution of η-precipitates as the aging temperature further increases. The desirable heterogeneous microstructure of the aged martensite matrix, soft reversed austenite and stable η-precipitates at 500 °C contributes to a high yield strength (~ 1 GPa, 25 °C; ~ 1.4 GPa, -196 °C) and a reasonable cryogenic impact toughness (~ 60 J, − 196 °C), which is mainly ascribed to the precipitation strengthening of η-precipitates, transformation-induced plasticity (TRIP) toughening effect from the lath-like reversed austenite and the increased misorientation toward high-angle grain boundary.