Abstract
The effects of Ag and/or Cu additions on the natural aging and precipitation hardening behavior of Al-Mg-Si alloys were investigated by using hardness test, differential scanning calorimetry (DSC), and transmission electron microscopy (TEM). Both Ag and Cu additions enhanced the hardening kinetics of Al-Mg-Si alloys during natural aging (NA) and artificial aging (AA) treatments. The strong interaction of Cu, Ag and Mg atoms is responsible for the improved precipitation kinetics of these alloys, resulting in a refinement of clusters and precipitates. The stronger interaction between Ag and Mg results in lower T4 hardness and higher AA hardness, compared to Cu. This is potentially beneficial for automobile applications where rapid hardening during paint baking is required. Both Ag and Cu additions reduce the detrimental effect of NA on subsequent AA, due to the formation of Ag or Cu-containing clusters. The clear advantage of Ag addition, compared to Cu, is the improvement of precipitation hardening response of Al-Mg-Si alloys.
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