Effect of addition sites on bioaugmentation of tea polyphenols-NZVI/PE composite packing: Nitrogen removal efficiency and service life

Abstract

Although efficient improvement of the nitrogen removal from wastewater by adding iron was achieved in wastewater process, the influence mechanism of addition sites is unclear. The study was based on the A/O-MBR treating simulated domestic wastewater, and tea polyphenol-nano zero-valent iron/polyethylene packing (TP-NZVI/PE) was added into the anoxic tank, aerobic tank and membrane effluent end of the process, respectively. The effect of the different addition sites on the nitrogen removal performance of A/O-MBR was investigated. Combine with the corrosion rate of NZVI on the packing surface to optimize TP-NZVI/PE addition site. The enhancement mechanism of TP-NZVI/PE under different addition site was explored through the calculation of the materials balance (carbon, nitrogen, phosphorus). The results showed that the pollutant removal of A/O-MBR was significantly increased with the TP-NZVI/PE added. In particular, the TP-NZVI/PE was added into the aerobic tank, and the pollutant removal rate was increased 31.71% (TN) and 53.00% (total phosphorus), respectively. Meanwhile, the service life of TP-NZVI/PE in the aerobic tank was 66 days. The anti-oxidation and dispersion of NZVI was improved with the encapsulation of tea polyphenols and support of packing, and it also played a certain slow-release effect, so that the service life of NZVI was further prolonged in aerobic condition. Combined with the material balance analysis, the result showed that the environmental structure made diversity in the aerobic tank by added the TP-NZVI/PE, and the simultaneous nitrification and denitrification process was achieved. The dependence of the denitrification process on the carbon source was greatly reduced. Besides, it promoted the adsorption and chemical precipitation process of the system for phosphor pollutant and achieved the denitrifying phosphorus removal performance.