Effect of Added Tetraalkylammonium Counterions on the Dilational Rheological Behaviors of N-Cocoyl Glycinate.

Abstract

Ion specific effect, which is also known as Hofmeister effect, has been reported in numerous systems including ionic surfactant aggregates. Acyl amino acid surfactants have attracted growing attentions in the field of novel surfactants research due to their environmentally benign characteristics. The objective of this study was to investigate the effect of different salts containing NH4+ and tetraalkylammonium (TAA+), where alkyl = methyl (TMA+), ethyl (TEA+), and propyl (TPA+), cations on the dilational rheological properties of interfacial film are stabilized by potassium N-cocoyl glycinate (KCGl). The interfacial behaviors were studied using oscillating drop shape analysis method. The interfacial tensions (IFTs) and dilational rheological parameters results illustrate that KCGl in the presence of salts has better interfacial activity and stronger intermolecular interaction, indicating that added cations contribute to denser molecular packing at oil-water interface. Ion specific effects were observed in the system. Among the cations, KCGl shows highest dilational modulus in the presence of NH4+. The overall interaction between cations and headgroups of KCGl decreases in the sequence NH4+ >TMA+ >TEA+ ≈TPA+, which follows Hofmeister series. The increasing hydrophobicity of TAA+ prevents the interaction between cations and KCGl's headgroup, and therefore prevent amphiphiles from packing closely at interface. The results present a theoretical origin for useful application of KCGl in cosmetics, petroleum and daily chemical industries.