Abstract
The PVC-PVDF-GO nanocomposites thin films were prepared by solution casting method. A thin film of Polyvinyl chloride (PVC), Polyvinylidene fluoride (PVDF), PVC-PVDF-GO was uniformly irradiated with a carbon ion beam at 70 MeV over a surface of 1 cm2 in a vacuum of almost 5 × 10−7 torr with ion fluencies of 1 × 1012 and 2 × 1013 ions/cm2. Fourier transform infrared (FTIR) spectroscopy was observed to track changes in the β-content, represented as F(β)%, during the recrystallization of PVDF after irradiation. At ambient temperature, the variation of dielectric constant and dielectric loss has been studied for pristine and irradiated samples. Ion beam irradiation caused significant changes to the dielectric constant and dielectric loss. After irradiation, the dielectric constant (ϵ′) increases at lower fluence (1 × 1012 ions/cm2), but decreases at higher fluence (2 × 1013 ions/cm2) in comparison with the pristine polymer samples. In PVDF, free radicals are generated by chain scission and cross-linking.
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