Abstract
Abstract Fractionation data of two poly(methyl methacrylate) samples prepared by suspension polymerization up to limiting conversion, in the presence of different amounts of 1-n-dodecanethiol, indicate that both samples have similar polydispersity factors, although the molecular weight distribution curve for the sample obtained with the highest chain transfer agent concentration is shifted to lower molecular weight values. The results obtained are qualitatively correlated with the high conversion polymerization theory proposed by Cardenas and O'Driscoll.
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