Editing of polymer backbones.

Abstract

Polymers are at the epicentre of modern technological progress and the associated environmental pollution. Considerations of both polymer functionality and lifecycle are crucial in these contexts, and the polymer backbone - the core of a polymer - is at the root of these considerations. Just as the meaning of a sentence can be altered by editing its words, the function and sustainability of a polymer can also be transformed via the chemical modification of its backbone. Yet, polymer modification has primarily been focused on the polymer periphery. In this Review, we focus on the transformations of the polymer backbone by defining some concepts fundamental to this topic (for example, 'polymer backbone' and 'backbone editing') and by collecting and categorizing examples of backbone editing scattered throughout a century's worth of chemical literature, and outline critical directions for further research. In so doing, we lay the foundation for the field of polymer backbone editing and hope to accelerate its development.