Ecological risk, source apportionment, and influencing factors of heavy metals in soil in a typical lead-zinc mining watershed, Guangxi, China

Abstract

Soil contamination by heavy metals (HMs) leads to significant decreases in soil ecosystem quality, seriously threatening human survival and development. Studies on soil HMs have focused on the sources, distributions, and influencing factors. However, soil HM migration and speciation, which indirectly affect HM distributions and their ecological risks, have often been overlooked. In this study, we investigated the links between the sources, distributions, and influencing factors of soil HMs, as well as their ecological risks at several levels, by analyzing soil samples collected from a Pb-Zn mining area. Soil column experiments were also performed to assess Pb leaching in the soil. The results indicate that soil HMs accumulated in front of the mountain river outlets, at the entrance of the underground river, and at soil depths of 0–40 cm. Cd and Pb were the main contributors to the high ecological risk in the soil, and As and Cr were the main contributors to cancer risk. The source analysis indicates that mining and smelting activities were the main sources of total soil HMs (32.55%), as well as the main sources of Sb (83.43%), Pb (68.65%), and Cu (45.37%). Mining activity and continuous riverine transport were the main sources of Cd (69.93%) and Zn (52.38%). These anthropogenic sources have major impacts on the ecological environment in the study area. Factors such as pH, clay and silt contents, soil organic matter content, and cation exchange capacity influenced the distributions and total amounts of Cu, Mn, Zn, and Pb species.