Eco-friendly Rot and Crease Resistance Finishing of Jute Fabric using Citric Acid and Chitosan

Abstract

Citric acid (CA) along with chitosan was used on bleached jute fabrics to impart anti crease and rot resistance properties in one step. The treatment was carried out by pad-dry-cure method in presence of sodium hypophosphite monohydrate catalyst. Curing at 150° Centigrade for 5 min delivered good crease resistant property (dry crease recovery angle is 244°) and high rot resistance simultaneously by a single treatment, which are durable for five washings with distilled water. Strength retention of jute fabric after 21 days soil burial was found to be 81 % and the loss (%) in strength due to this treatment was 15–18 %. The results showed that chitosan and CA treated-fabric exhibited higher rot resistance (as indicated by soil burial test) when compared to either CA or chitosan by individual treatment. The effect of CA and chitosan combination on the resistance to rotting of jute fabric was found to be synergistic which is higher than the sum of the effects of individual chemicals. CA possibly reacts with hydroxyl groups in cellulose or chitosan to form ester. The CA and chitosan finished fabric has adverse effect on stiffness. Thermal studies showed that final residue left at 500° C was much higher for CA and chitosan treated fabric than untreated jute fabric. FTIR spectroscopy suggested the formation of ester cross-linkage between the jute fibre, CA and chitosan and hence it is understood that this rot resistant finish on jute fabric become durable by this mechanism.