Abstract
Eco-compatible activation methods in Suzuki–Miyaura cross-coupling reactions offer challenging opportunities for the design of clean and efficient synthetic processes. The main enabling technologies described in the literature are microwaves, ultrasound, grinding (mechanochemistry) and light. These methods can be performed in water or other green solvents with phase-transfer catalysis or even in solventless conditions. In this review, the authors will summarize the progress in this field mainly from 2010 up to the present day.
Highlights
The present review deals with the use of non-conventional methods for Suzuki–Miyaura reactions (SMC) [1]
Every year of the last decade has seen around 50–60 surveys highlight the versatility and the peculiar advantages of SMC
The most important eco-compatible activation methods in SMC, including microwaves (MW), ultrasound, grinding, light, and the main advances made over last few years will be described
Summary
Some Insights into the Suzuki–Miyaura reaction 2. MW Irradiation in Homogeneous Catalyzed SMC 2.1.1. SMC from Arene to Heterocycle Decoration 2.1.2. Moving from Homogeneous to Heterogeneous Catalysis in MW Promoted SMC 2.3. Solid Supported Pd Catalyzed MW Promoted SMC Use of MWs for the Synthesis of the Catalysts for the SMC Reaction 3. Ultrasound Assisted Heterogeneous Preparation of Catalysts Suitable for SMC Reactions 3.3. Ultrasound Assisted Heterogeneous Catalyst Preparation for MW Promoted SMC Reactions 4. When the SMC Reaction is Driven by Light
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