Eco-friendly natural rubber-based hydrogel loaded with nano-fertilizer as soil conditioner and improved plant growth

Abstract

This study addresses the dual challenge of agricultural cost and waste management by harnessing agrarian waste to produce nano-fertilizers (NF) to enhance crop yield while mitigating environmental impacts. Recognizing the limitations of traditional hydrogels' non-biodegradability and their inability to sustain root zone moisture and nutrient levels, we developed an LNR/AAc/pectin hydrogel. This innovative hydrogel offers a viable solution that provides a consistent NF supply and improves water retention efficiently. Additionally, we utilized Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy-energy dispersive x-ray (SEM-EDX), and thermogravimetric analysis (TGA) to analyze the hydrogel's structure, stability, and form. Transmission electron microscopy (TEM) and X-ray fluorescence spectroscopy (XRF) were employed to ascertain the NF concentration. The optimization of the hydrogel's swelling and NF release was conducted through a 5-level, 2-factor Response Surface Methodology (RSM), focusing on the effects of the AAc: LNR ratio and pectin weight while maintaining constant concentrations of potassium persulfate (KPS) and MBA. Results revealed a high correlation between predicted and experimental values, with determination coefficients (R2) of 0.9982 for swelling and 0.9979 for NF release. Furthermore, the hydrogel exhibited a 96.30 % biodegradation rate after 120 days of soil burial. Our findings demonstrate the hydrogels' potential to significantly impact farming and gardening by ensuring a sustainable supply of nutrients to enhance soil moisture retention.