Abstract

One of the main concerns in the modern cement industry is on reducing the CO2 emissions. As an alternative binder of Portland cement, belite-ye’elimite-ferrite (BYF) cement can reduce the CO2 emission by over 20% due to its benefits concerning the chemical composition and industrial processing. This paper proposed a ternary cementitious system consisting of BYF cement, limestone filler, and silica fume. The ternary system containing 10% limestone and 5% silica fume showed higher compressive strength than the BYF cement, while the CO2 emission factor further reduced by ∼13%. The effect of limestone and silica fume on the hydration was studied. It was found that the hydration reaction of limestone induced the formation of hemicarbonate and stabilized ettringite. This reaction formed dissolution rims around the limestone particles. At the early hydration ages, silica fume was bonded by aluminum hydroxide, forming aluminate silicate hydrate. During the hydration, the silicate dissolved and reacted with the hy...

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