Abstract

The activity coefficients of the solvent (1n f1) have been determined by ebulliometry for solutions of certain salts in benzene and CCl4. The results, together with data in the literature have been used to calculate the second and third virial coefficients of 1n f1 for a number of salt solutions in benzene, CCl4, and dioxane. It is shown that the positive deviations from ideality in such solutions depend on the nature of the anion, the length of the amine radical, the temperature, and the nature of the solvent.

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