Easily Repairable and High-Performance Carbon Nanostructure Absorber for Solar Photothermoelectric Conversion and Photothermal Water Evaporation

Abstract

Carbon materials are a category of broadband solar energy harvesting materials that can convert solar energy into heat under irradiation, which can be used for photothermal water evaporation and photothermoelectric power generation. However, destruction of the carbon nanostructure during usage will significantly decrease the light-trapping performance and, thus, limit their practical applications. In this article, an easily repairable carbon nanostructure absorber with full-solar-spectrum absorption and a hierarchically porous structure is prepared. The carbon absorber shows a superhigh light absorption of above 97% across the whole solar spectrum because of multiple scatterings within the carbon nanostructure and photon interaction with the carbon nanoparticles. The excellent light absorption performance directly leads to a good photothermal effect. As a consequence, the carbon absorber integrated with a thermoelectric module can obtain a large power (133.3 μW cm-2) output under 1 sun. In addition, the carbon absorber combined with the sponge can achieve a high photothermal water evaporation efficiency of 83.6% under 1 sun. Its high-efficiency solar-to-electricity and photothermal water evaporation capabilities demonstrate that the carbon absorber with superhigh absorption, simple fabrication, and facile repairability shows great potential for practical fresh water production and electric power generation.