Abstract
In the molecule of the title compound, C14H12FNO2, the aromatic rings are oriented at a dihedral angle of 48.17 (1)°. An intramolecular O—H⋯N hydrogen bond results in the formation of a six-membered ring. The title molecule is a phenol–imine tautomer, as evidenced by the C—O [1.351 (3) Å], C—N [1.282 (3) Å], and C—C [1.416 (3)–1.445 (3) Å] bond lengths. In the crystal, molecules are linked by intermolecular C—H⋯π interactions.
Highlights
The authors acknowledge the Faculty of Arts and Sciences, Ondokuz Mayıs University, Turkey, for the use of the Stoe IPDS II diffractometer
In the molecule of the title compound, C14H12FNO2, the aromatic rings are oriented at a dihedral angle of 48.17 (1)
H atoms treated by a mixture of independent and constrained refinement
Summary
Key indicators: single-crystal X-ray study; T = 296 K; mean (C–C) = 0.003 A; R factor = 0.035; wR factor = 0.104; data-to-parameter ratio = 8.3. In the molecule of the title compound, C14H12FNO2, the aromatic rings are oriented at a dihedral angle of 48.17 (1). An intramolecular O—HÁ Á ÁN hydrogen bond results in the formation of a six-membered ring. The title molecule is a phenol–imine tautomer, as evidenced by the C—O [1.351 (3) A ], C—N [1.282 (3) A ], and C—C [1.416 (3)– 1.445 (3) A ] bond lengths. Related literature The present work is part of a structural study of Schiff bases, see: Ozek et al (2007); Odabasoglu et al (2007); Albayrak et al (2005). See: Ozek et al (2007, 2009)
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