Abstract

We investigate the potential link between Kramer's treat- ment of rate processes and the molecular-kinetic theory of wetting. The results of recent large-scale simulations of dynamic wetting are used to illustrate and validate our analysis. We find that both theo- ries predict that, for a given driving force, the velocity of the contact line is inversely proportional to the viscosity. They also predict that the velocity will depend with a negative exponent on the strength of solid-liquid interactions, which for simple systems can be represented to good approximation by the reversible work of adhesion Wa 0 .

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