Abstract
Thiophosgene, Cl 2CS, has been excited with ps laser pulses in bulbs and a continuous supersonic expansion to nominal single vibronic levels in the B ̃ ( 1 A 1) state, and its emission spectra, temporal fluorescence decay profiles and quenching constants measured. Bound bright vibronic B̃ states decay exponentially by primarily radiative means. Further evidence is found of non-radiative passage of a subset of bright B̃ states to a dark portion of the B̃ state hypersurface.
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