Abstract

Abstract The dynamics of several thermal and photochemical reactions in the solid-state are investigated by laser Raman spectroscopy, electronic spectroscopy and a rigid-body motion analysis of the thermal parameters of x-ray diffraction studies. Raman phonon spectroscopy along with electronic emission spectroscopy is used to identify the reaction mechanism. The possibility of occurence of any lattice and/or molecular intermediate is examined, by Raman spectroscopy of both phonons and intramolecular vibrations. The new concept of phonon-assisted reaction is tested by examining the role of an overdamped oscillation in a thermal reaction and that of a strong electron-phonon coupling in a photochemical reaction.

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.