Dynamics of permeable particles in concentrated suspensions

Abstract

We calculate short-time diffusion properties of suspensions of porous colloidal particles as a function of their permeability, for the full fluid-phase concentration range. The particles are modeled as spheres of uniform permeability with excluded volume interactions. Using a precise multipole method encoded in the HYDROMULTIPOLE program, results are presented for the hydrodynamic function, H(q) , sedimentation coefficient, and self-diffusion coefficients with a full account of many-body hydrodynamic interactions. While self-diffusion and sedimentation are strongly permeability dependent, the wave-number dependence of the hydrodynamic function can be reduced by appropriate shifting and scaling, to a single master curve, independent of permeability. Generic features of the permeable sphere model are discussed.