Abstract

The dynamics of the bromate-1,4-cyclohexanedione reaction and its ferroin catalyzed version in a continuously fed stirred tank reactor are reported. In the ([Br −] 0, [H 2SO 4] 0) and ([Br −] 0, [ferroin] 0) planes steady-state bistability and oscillations are observed. Close to the upper [Br −] 0 limit of the oscillatory domain the oscillations become aperiodic. By increasing the [ferroin] 0 the characteristic of the oscillations switches from ‘uncatalyzed’ to ‘catalyzed’-type. Additionally, the effects of the bromide ions and ferroin on the batch dynamics are investigated.

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