Dynamics of a droplet on a polymer brush in channel flow

Abstract

Using dissipative particle dynamics, we simulate an immiscible oil droplet on a polymer brush under a channel flow. Above a critical flow velocity, the droplet slides on the brush surface with contact angle hysteresis. Interestingly, we found the critical sliding velocity to be constant across droplet sizes and interphase interactions. Further increase in flow velocity results in droplet detachment and liftoff from the brush surface. Under poor solvent conditions, large droplets may deform into an airfoil shape, increasing the critical liftoff velocity. On an oleophilic brush, the droplet desorbs and spreads, instead of liftoff. Together, our results show surprisingly rich dynamics coupling three-way interactions between either soft or liquid phases. The present study has implications on the design of polymer brushes, as well as the removal of droplets from soft surfaces using hydrodynamics.