Dynamic vulcanization of reclaimed tire rubber and high density polyethylene blends

Abstract

Dynamic vulcanization of reclaimed tire rubber (RTR) and HDPE blends was reported. The effect of blend ratio, methods of vulcanization, i.e. sulphur, peroxide, and mixed system and the addition of compatibilizer on mechanical, thermal, and rheological properties were investigated. The blend with highest impact strength was obtained from 50/50 RTR/HDPE vulcanized by sulphur. Increasing the RTR content to more than 50% resulted in a decrease in the impact strength of blend, most likely due to the increasing carbon black content. For tensile strength, the presence of rubber and carbon black, however, unavoidably caused a drop in this property. Comparing among three methods of vulcanization, sulphur system seems to be the most effective method. Results from solvent swelling ratio, glass transition temperatures and viscosity indicated that the sulphur vulcanization created the highest degree of cross-link and filler–matrix interaction in the RTR/HDPE blend. Morphology of the blends was also assessed by scanning electron microscopy (SEM).