Abstract

The dumbbell (DB) ZnO bipod crystal is directly grown from acetate anion intercalated Zn based hydroxyl double salts (Zn-HDS). Our results suggest that the (0001)-to-(0001) plane orientation of the DB ZnO crystal comes from the acetate anions intercalated into the Zn-HDS. The DB ZnO crystal is dynamically changed to tube, nanoplate, and the new Zn-HDS with interlayer spacing of 20.0Å by etching the (000-1) surface.

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