Abstract
Abstract The rate of the degenerate isomerization of N-hexafluoroisopropylidene-N’,N’-dimethyl-ρ-phe-nylenediamine was measured by high-pressure 19F NMR spectroscopy in a viscous hydrocar-bon, 2,4-dicyclohexyl-2-methylpentane. Pressure-induced retardations that cannot be rationalized within the framework of the transition state theory (TST) were observed, and it was concluded that the reaction was cast into the TST-invalid nonequilibrium conditions by high pressure.
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