Abstract

The creep and relaxation of domain walls under an ac electric field that are observed in an ideal model system, periodically poled superionic KTiOPO4 (KTP), appear to occur in different regimes that are separated by a dynamic phase transition at a well-defined frequency, f m = 0.003 Hz, at temperature T = 233 K. The power-law dispersion of the creep susceptibility, χ ∝ 1 + (iωτ)− β (with β ≈ 0.4), and the large nonlinearity encountered for f<f m is contrasted with the Cole–Cole-type relaxational dispersion, χ ∝ [1 + (iωτ)1− α −1 (with α ≈ 0.3), for f > f m. Similar creep-to-relaxation transitions are observed at low frequencies in other ferroic systems with weak disorder: the multidomained uniaxial relaxor Sr0.69Ba0.31Nb2O6 (SBN), the quantum ferroelectric domain state of SrTi18O3 (STO18) and the superferromagnetic nanoparticle system [(Co80Fe20(1.4 nm)/Al2O3(3 nm)]10, which appear to belong to the same dynamical universality class.

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