Dynamic Optimization of Lurgi Type Methanol Reactor Using Hybrid GA-GPS Algorithm: The Optimal Shell Temperature Trajectory and Carbon Dioxide Utilization

Abstract

At present, methanol is mostly produced from syngas, derived from natural gas through steam methane reforming (SMR). In a typical methanol production plant, unreacted syngas is recycled for mixing with natural gas and both used as fuel in the reformer furnace resulting in carbon dioxide (CO2) emissions from the flue gases emitted into the atmosphere. However, CO2 can be captured and utilized as feedstock within the methanol synthesis process to enhance the productivity and efficiency. To do so, dynamic optimization approaches to derive the ideal operating conditions for a Lurgi type methanol reactor in the presence of catalyst deactivation are proposed to determine the optimal use of recycle ratio of CO2 and shell coolant temperature without violating any process constraints. In this context, this study proposes a new approach based on a hybrid algorithm combining genetic algorithm (GA) and generalized pattern search (GPS) derivative-free methodologies to provide a sufficiently good solution to this dynam...