Abstract

Based on the cooperative dynamic Jahn-Teller effect, a universal model of superconductivity is sketched which accounts for many aspects of conventional BCS and high Tc superconductors. Within the quasi-molecular approximation, a real space vibronic coupling of degenerate (or nearly degenerate) electronic states to anharmonically mixed nuclear distortions is shown to lead to electron pairing. The crossover from electron-phonon behavior to electronic behavior as a function of Jahn-Teller coupling and anharmonic mixing is illustrated for the case of a CuO4 cluster having D4h symmetry.

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