Abstract

Oxidation-Kinetics of cyclamate by bromamine-T (BAT) in HClO4 medium catalyzed by RuCl3 exhibits a first-order dependence on [BAT]0, fractional-order on both [Cyclamate]0 and [RuCl3], and inverse fractional-order on [HClO4]. RuCl3 catalyst accelerated the reaction by a splendid 48 times. Plausible mechanism and related rate law have been deduced. The Stoichiometry of the reaction is:

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