Dynamic Heterogeneity in a Glass Forming Fluid: Susceptibility, Structure Factor, and Correlation Length

Abstract

We investigate the growth of dynamic heterogeneity in a glassy hard-sphere mixture for volume fractions up to and including the mode-coupling transition. We use an 80,000 particle system to test a new procedure to evaluate a dynamic correlation length ξ(t): we determine the ensemble independent dynamic susceptibility χ(4)(t) and use it to facilitate evaluation of ξ(t) from the small wave vector behavior of the four-point structure factor. We analyze relations between the α relaxation time τ(α), χ(4)(τ(α)), and ξ(τ(α)). We find that mode-coupling-like power laws provide a reasonable description of the data over a restricted range of volume fractions, but the power laws' exponents differ from those predicted by the inhomogeneous mode-coupling theory. We find ξ(τ(α))~ln(τ(α)) over the full range of volume fractions studied, which is consistent with an Adam-Gibbs-type relation.