Dynamic heterogeneity and collective motion in star polymer melts.

Abstract

While glass formation of linear chain polymer melts has widely been explored, comparatively little is known about glass formation in star polymer melts. We study the segmental dynamics of star polymer melts via molecular dynamics simulations and examine the cooperative nature of segmental motion in star melts. In particular, we quantify how the molecular architecture of star polymers, i.e., the number of arms and the length of those arms, affects the glass transition temperature Tg, the non-Gaussian nature of molecular displacements, the collective string-like motion of monomers, and the role of chain connectivity in the cooperative motion. Although varying the number of arms f and the molecular mass Ma of the star arms can significantly influence the average star molecular shape, all our relaxation data can be quantitatively described in a unified way by the string model of glass formation, an activated transport model that derives from the Adam-Gibbs model, where the degree of cooperative motion is identified with the average length L of string-like particle exchange motions observed in our simulations. Previous work has shown the consistency of the string model with simulations of linear polymers at constant volume and constant pressure, as well as for thin supported polymer films and nanocomposites with variable polymer-surface interactions, where there are likewise large mobility gradients as in the star polymer melts studied in the present paper.