Abstract

AbstractWork carried out in the last decade or so suggests that the simulators for multiphase flow in porous media should include an additional term, namely a dynamic coefficient, as a measure of the dynamic effect associated with capillary pressure. In this work, we examine the dependence of the dynamic coefficient on temperature by carrying out quasi‐static and dynamic flow simulations for an immiscible perchloroethylene–water system. Simulations have been carried out using a two‐phase porous media flow simulator for a range of temperatures between 20 and 80°C. Simulation domains represent 3‐D cylindrical setups used by the authors for laboratory‐scale investigations of dynamic effects in two‐phase flow. Results are presented for two different porous domains, namely the coarse and fine sands, which are then interpreted by examining the correlations between dynamic coefficient(s) and temperature, time period(s) required for attaining irreducible water saturation, and the dynamic aqueous/nonaqueous phase saturation and capillary pressure plots. The simulations presented here maintain continuity from our previous work and address the uncertainties associated with the dependency of dynamic coefficient(s) on temperature, thereby complementing the existing database for the characterization of dynamic coefficients and subsequently enabling the users to carry out computationally economical and reliable modeling studies. © 2012 The Authors. AIChE Journal, published by Wiley on behalf of the AIChE. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. AIChE J, 58: 1951–1965, 2012

Highlights

  • Flow of immiscible fluids in porous media is of special importance in soil science as well as in chemical, environmental, construction, and petroleum industries

  • Thereafter, we discuss the effects of temperature on dynamic coefficients for both the coarse and fine sands. 3-D contours of saturation have been presented for both the domains to show the effects of temperature on the times required for the flow to reach equilibrium

  • Simulations have been carried out in this work to quantify the effects of temperature on the dynamic capillary pressure and subsequently dynamic effects on two-phase porous flow in cylindrical domain

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Summary

Introduction

Flow of immiscible fluids in porous media is of special importance in soil science as well as in chemical, environmental, construction, and petroleum industries. The immiscible flow of nonaqueous phase liquids (NAPLs) commonly occurs in various subsurface conditions, groundwater remediation operations, and in oil recovery processes. In such systems, capillary pressure plays a crucial role in determining the motion of fluids within the porous media.[1,2,3,4,5,6,7,8] In addition, temperature variation may affect such flows where the hydraulic properties of the porous media such as hydraulic conductivity and water retention are temperature. The conventional relations of the capillary pressure are functions of wetting-phase saturation (Pc-S relationships) and differences between the average pressures for oil/nonwetting and the water/wetting,[15,16] which can be mathematically expressed as

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