Abstract
Programmable dynamic catalysts provide a promising means to break linear scaling relations and exceed theoretical Sabatier volcano performance peaks. In this issue of Chem Catalysis , Gathmann et al. demonstrate how reactions can attain greater turnover frequency enhancements if the energies of consecutive intermediates are shifted in opposite directions to an external perturbation. Programmable dynamic catalysts provide a promising means to break linear scaling relations and exceed theoretical Sabatier volcano performance peaks. In this issue of Chem Catalysis , Gathmann et al. demonstrate how reactions can attain greater turnover frequency enhancements if the energies of consecutive intermediates are shifted in opposite directions to an external perturbation.
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