Abstract

Novel elastomer/modified carbon nanotube nanocomposites were prepared by melt mixing ethylene vinyl acetate (EVA) matrix with dye-grafted multiwalled carbon nanotubes (MWCNTs, CNTs in short). The latter were prepared by spontaneous reactions of diazotized Azure A (AA-N2+), Neutral Red (NR-N2+) and Congo Red (CR-N2+) dyes with CNTs in water at RT. The dispersion of the dye-modified CNTs was facilitated with cholesteryl 1-pyrenecarboxylate (PyChol) surfactant. The EVA/modified CNT nanocomposites were employed as optothermal actuators. The photo-actuation measurements were performed on the un-stretched as well as the stretched strips of pristine EVA and EVA/CNT-dye nanocomposites using a dynamic mechanical analyzer (DMA) equipped with a red light emitting diode (red LED) at a wavelength of 627 nm illuminated either 10 s or 30 s. The concentration of modified dyes, the use of PyChol surfactant and the applied pre-strain were the parameters investigated in this work.To sum up, the nanocomposites prepared so far could be regarded as promising optothermal actuators used for touch displays visually impaired people.

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