Dy3+ ions doped (Na2O/NaF)-Gd2O3–P2O5 glasses for solid state lighting material applications

Abstract

Oxide and oxyfluoride glasses doped with Dy3+ ions were prepared by melt-quenching method with glass matrix 17Na2O: 17Gd2O3: 65P2O5:1Dy2O3 and 17Na2O: 17Gd2O3: 65P2O5:1Dy2O3. The work emphasizes the effect of fluoride and oxide content in the glass and its cause for photoluminescence and their physical properties. Oxide glass show higher density, molar volume and refractive index values than compared to oxyfluoride glass. Judd-Ofelt (JO) theory was employed to understand the oscillator strength of particular transition observed in absorption spectra in UV–Vis–NIR ron. Judd-Ofelt theory provides information on JO parameters such as Ωλ (λ = 2,4,6) which shows Ω2 > Ω4 > Ω6 trend for both these oxide and oxyfluoride glasses. The luminescence properties were studied for 574 nm (4F9/2 → 6H13/2) emission peak by exciting at appropriate wavelength (349 nm for corresponding to (6H15/2 → 6P7/2) and investigating radiative properties for other emission peaks observed from the spectra using JO parameters. The emission spectra, showed two major peaks corresponding to 482 nm blue emission (4F9/2 → 6H15/2) and 574 nm yellow emission (4F9/2 → 6H13/2).Stimulated emission cross section (σ) shows higher value for 4F9/2 → 6H13/2 transition for oxide and oxy-fluoride glasses, whereas oxyfluoride glass surpasses oxide glass. Similarly the emission intensity of oxyfluoride glasses show higher than oxide when monitored for Gd3+ ions (275 nm) and Dy3+ ions (349 nm). The experimental lifetime shows 0.539 ms and 0.540 ms for oxide and oxyfluoride glass sample, respectively. The x, y color coordinates under 349 nm excitation wavelength were (0.38, 0.43) for both glass samples. The Y/B ratio results suggests that the Gd3+ shows more covalency than compared to Dy3+ ions in the oxide glass whereas vice-versa in case of oxyfluoride glass hence, higher emission intensity at 574 nm. The data obtained from these investigations confirms that the present Dy-doped oxide and oxyfluoride glasses could be potential candidate for efficient luminescence materials for solid-state lighting applications, especially for white LEDs.