Abstract

Abstract The resistance of very high volume fly ash cement pastes and mortars activated by Na 2 SO 4 has been monitored following immersion for up to 90 d in 0.1 M HCl, 4.4% Na 2 SO 4 and ASTM-compliant sea water. Changes in the compressive strengths of mortars and in crystalline phases, bond environments, and the microstructure of pastes following immersion were monitored. Experiments were repeated with a commercially available sulfate resistant cement. Both cements were found to present adequate resistance to both sea water and the Na 2 SO 4 solution. However, both were severely degraded by acid immersion. Differences in potential degradation mechanisms based on the chemistry of the fly ash binder and the reference cement are discussed.

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