Durability of sorption of per- and polyfluorinated alkyl substances in soils immobilized using common adsorbents: 2. Effects of repeated leaching, temperature extremes, ionic strength and competing ions

Abstract

Persistent use of aqueous film-forming foams containing per- and polyfluoroalkyl substances (PFASs) in firefighting has led to severe contamination of soil and aquifers at training sites, which makes remediation of such sites a necessity. We investigated the persistence of binding of PFASs to a mixed-mode remediation agent including repeated leaching, and the effects of competing ions and temperature extremes. The sorbent (RemBind®) was added to PFAS-contaminated soils and standard leaching procedures - the U.S. EPA Multiple Extraction Procedure and the U.S. EPA Leaching Environmental Assessment Framework were applied to quantify desorption of PFASs from remediated and unremediated soils. Possible desorption by competing anions such as orthophosphate (H2PO4−) and humic acid (HA) were assessed, and effects of temperature extremes and ionic strength were also investigated. These are the main environmental factors that could potentially affect desorption of PFASs over time at a typical site. Desorption of PFASs from unremediated soils was related to C-chain length with short-chain PFASs easily desorbed and leached. PFASs with carboxylic head groups leached faster than those with a sulfonic acid head group. The sorbent retained PFASs strongly and reduced desorption and leaching from remediated soils by 92 to 99.9%. There were no detrimental effects on desorption of PFASs from temperature extremes or changes in ionic strength. In remediated soils, effects of competing ions were also absent or minimal. However, in unremediated soils increasing concentrations of orthophosphate and HA increased leaching of some long-chain PFASs. While short-term laboratory desorption experiments cannot exactly mimic long-term field conditions, these results provide site owners and regulatory authorities with a high level of confidence that PFASs binding by RemBind® is predicted to be persistent in the long term. However, to give the greatest level of confidence, these simulations should be validated under field conditions for at least several years.