Abstract

Possibility of hybrid catalytic systems for ethylene dimerization and copolymerization including Ti (On-Bu)4, (C5H5)4Zr, and methylaluminoxane formation has been proved. Properties of copolymers formed in the presence of these systems were studied. It was shown that the main advantage of new catalytic systems is their flexibility that allows them to be used for production of a wide assortment of polyethylene. Developed catalytic systems make possible the production of polyethylene all branded assortment from ethylene as the only feedstock according to the one-reactor technological scheme.

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