Abstract

According to quantum mechanics, the commutation property of the energy Hamiltonian with the momentum operator should give the definite values not only for energy but also for the momentum quantum levels. A difficulty provided by the standing-like boundary conditions of the electron gas is that the Hamiltonian eigenfunctions are different than eigenfunctions of the momentum operator. In results the electron momenta are obtained from the correspondence rule between the classical and quantum mechanics given by Landau and Lifshits. As a consequence the statistics of solutions representing not only the energy values but also the electron momenta should be taken into account. In the Heisenberg picture of quantum mechanics, the momenta are easily obtained because the electron oscillators are there directly considered. In fact, the Hamiltonian entering the Heisenberg method can be defined in two different ways each giving the set of the electron energies known from the Schr?dinger’s approach.

Highlights

  • We had a competition of the Schrödinger and Heisenberg formalisms in their approach to develop the modern quantum mechanics

  • In results the electron momenta are obtained from the correspondence rule between the classical and quantum mechanics given by Landau and Lifshits

  • In the Heisenberg picture of quantum mechanics, the momenta are obtained because the electron oscillators are there directly considered

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Summary

Introduction

We had a competition of the Schrödinger and Heisenberg formalisms in their approach to develop the modern quantum mechanics. Suitable for the oscillatory examination, became the Heisenberg theory and an approach to it presented in [7] The both methods of quantum mechanics could be examined for a non-interacting electron gas case. In effect the electron wave functions represent the standing waves and they are not the eigenfunctions of the momentum operator, contrary to situation due to the Bloch’s boundary conditions applied usually to solids In this second case, the requirement of a finite and strictly one-dimensional gas model cannot be satisfied. The electron momenta obtained with the aid of the Heisenberg method are found identical with those deduced with the aid of the Schrödinger model for the low quantum numbers n; see Sec. 5 This imposes a question of statistics with which both the energy and momenta of free-electron particles can be satisfactorily considered. An alternative method to Schrödinger’s—much suitable for the oscillatory examination—is that of Heisenberg; see e.g. [7] [9]

Schrödinger’s Approach to the Free-Electron Particles
Oscillating Character of Electrons Described by ψ n and E n
Heisenberg Approach Applied to the Electron Oscillators
An alternative Heisenberg Treatment of Free Electrons in the Potential Box
Possible Duality of Statistics Applied to the Electron Quantum Levels
Summary
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