Abstract

The Presciano spring system (Central Italy) is fed by a fractured carbonate regional aquifer and shows peculiar hydrogeological, physicochemical, hydrogeochemical and biological features that led to hypothesis about local superimposition of a dual groundwater flow system. The components of this system are fast-flow and baseflow groundwater paths. Hydrogeochemical and isotopic (δ18O and δD for H2O, and δ34\( {\text{S}}_{{{\text{SO}}_{ 4} }} \) and δ18\( {\text{O}}_{{{\text{SO}}_{ 4} }} \)) data were used to test this conceptual model. Differences in physico-chemistry and ion concentrations were recorded for two main spring sectors, attributable to different groundwater flowpaths. Environmental isotope analyses allowed distinguishing different recharge areas for the two groups: more depleted values (−10.4 ‰ δ18O and −71 ‰ δD) indicated the existence of a flowpath influenced by a higher elevation recharge area, whereas enriched isotope signals (−9.9 ‰ δ18O and −66 ‰ δD) supported a regional recharge area of local water infiltration. The existence of a dual flow system is also reflected in the relationship between SO42− concentration and SO42− isotope data. The isotopic pattern of SO42− reflects the seasonal contributions by the two flow paths to the springs: after snowmelt, the isotopic sulphate value in the spring outlet is very similar to the spring sector fed by the fast flow component, while, after the spring exhaustion period, its isotopic composition is very similar to the base flow spring sectors fed by the fracture network. The influence of the different flowpaths has also been highlighted by changes in water isotope composition after the 2009 L’Aquila earthquake in this area: the strong homogeneous response of the spring system can be attributed to a cleaning of the fracture system, which affected the aquifer at regional scale. Additional investigations adopting the geoelectrical tomography technique highlighted the possibility of the existence of a buried karst channel or at least high-permeability shear zone at the contact between the carbonate aquifer and the fluvio-lacustrine quaternary deposits, where the spring system is located. Biological indicators, such as groundwater copepods also showed a response to the dual flowpath regime. The results of this study have great relevance for a better management of the Presciano spring habitat, which is increasingly threatened by anthropogenic disturbance.

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