Abstract
We report novel dual-responsive plasmonic core–shell anisotropic nanostructures composed of gold nanorod (AuNR) and responsive polyaniline (PANI) shells with plasmonic mode appearance reversibly modulated through orthogonal stimuli (i.e., electrical potential and pH change). In this system, the PANI shells provide AuNR cores with three different refractive index environments depending on stimuli (pH and electrical potential). Therefore, no additional secondary responsive component is necessary to induce the dual-responsive properties of AuNR cores. Furthermore, in this study, dual-responsive properties can be realized for nanostructures fixed on substrates, whereas previously reported dual-responsive plasmonic systems can only be controlled in solution. Here, the highest localized surface plasmonic resonance (LSPR) shift of the AuNR cores can be induced by changing both local pH and applying electric potential. Notably, a significant plasmon band shift by 107 nm is realized with only 8 nm thick PANI shell...
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