Dual-responsive polyacrylonitrile-based electrospun membrane for controllable oil-water separation

Abstract

Membrane separation based on smart materials with responsive wettability has attracted great attention due to the excellent performance of controllable oil-water separation. Herein, responsive copolymer originated from N-isopropylacrylamide and 2-(dimethylamino) ethyl methacrylate was synthesized and electrospun with polyacrylonitrile to fabricate smart composite membrane. The introduction of the responsive copolymer endowed the membrane with stimuli-responsive wettability to pH and temperature. Specifically, at the initial state, water was selectively blocked while oil passed through the membrane. After treatment with acidic water or CO2, the reverse separation was realized due to the protonation of the tertiary amine group in the copolymer. Water was selectively passed through the membrane after heat treatment because of the structural change of membrane upon temperature. The developed membrane was able to separate different types of oil-water mixtures and surfactant-stabled emulsions with high efficiency. Additionally, two membranes controlled by temperature and pH were designed to construct a logic AND gate for oil-water separation, and the results demonstrated that only the temperature and acidity of the solution were simultaneously satisfied, the water could flow through the valve combination, and such capability made this smart membrane great potential for remotely controlling the oil-water separation process.