Dual-Mode Circularly Polarized Light Emission and Metal-Enhanced Fluorescence Realized by the Luminophore-Chiral Cellulose Nanocrystal Interfaces.

Abstract

Circularly polarized (CP) light has attracted wide attention for its great potential in broad applications. However, it remains a challenge to generate left-handed and right-handed circularly polarized (LCP and RCP) light from cellulose nanocrystal (CNC)-based materials only with an intrinsic left-handed chiral structure, owing to the pattern of CP light emission primarily based on the chirality of materials. Herein, a separation structure of luminophore layers and chiral CNCs was provided to achieve dual-mode CP light emission by building a luminophore-chiral CNC interface. By directly exciting the back and front of two-layer films, LCP and RCP light could be easily emitted without any assisting means and specific setting angles. In addition, owing to the formation of the luminophore-chiral CNC interface, metal-enhanced fluorescence (MEF) was achieved to offset the brightness loss caused by circular polarization. By incorporating gold triangular nanoprisms in CNC chiral layers, the fluorescence enhancement of the ensemble was as high as 6.5-fold. The decisive role of the luminophore-chiral CNC interface in enhancing luminescence and dual-mode CP light emission was carefully investigated by contrasting the systems with and without luminophore-chiral CNC interfaces in this study. We believe that this dual-mode CP light emission film with MEF enables a promising approach to extending the application of CP light materials.