Abstract
A dual-mechanism energy storage strategy isproposed, involving the electrochemical process of sodium ion battery (SIB) and sodium metal battery (SMB). This strategy is expected to achieve a higher capacity than SIB, and obtain dendrite-free growth of SMB with a well-designed anode. Here, self-constructed bismuth with "sodiophilic" framework and rapid ion transmission characteristics is employed as the sodium host (anode) integrating alloy/de-alloy and plating/stripping process that suppresses the dendrite growth and overcomes the limited capacity of traditional anode. Benefited from this, the capacity (capacity contributed by alloy and plating of sodium in total) of 2000mAhg-1 can be reached, which can retain up to 800h at 1Ag-1 . Also, the capacity of 3100mAhg-1 can be achieved that is ≈7.7 times than that of alloyed-bismuth (Bi). This work proposes a dual-mechanism strategy to tackle the dilemma of high-performance sodium (Na) storage devices, which opens a new avenue for the development of next-generation energy storage device.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
