Dual-functional fluorescence sensors based on 3D lanthanide metal–organic framework and its mixed matrix membrane

Abstract

A new lanthanide metal–organic framework (Ln-MOF) {[Eu(DPB)(H2O)](Me2NH2+)}n (1) (H4DPB = (1,1′:3′,1′’-terphenyl)-3,3′’,5,5′’-tetracarboxylic acid）was synthesized under solvothermal conditions and presented a fascinating three-dimensional (3D) framework with 4,8-connected diamond topology, which were built from Eu3+ ions and tetra carboxylate groups. 1 showed strong red luminescence emission in the solid state at room temperature and exhibited good stability in different solvents. 1 could be used as a multi-responsive luminescent sensor for hemin and p-Nitrophenol (4-NP) with detection limits of 3.91 × 10−6 M and 1.98 × 10−4 mM, respectively. Moreover, using 1 as a filler and poly (vinylidene difluoride) (PVDF) as matrix, a mixed matrix membrane 1@PVDF was successfully prepared. 1@PVDF also exhibited fluorescence emission comparable to that of 1 and could be used for hemin and 4-NP sensing with good selectivity and remarkable recyclability.