Droplet-like Defect Annihilation Mechanisms in Hexagonal Cylinder-Forming Block Copolymers.

Abstract

The annihilation of typical individual defects in hexagonal cylinder-forming block copolymers is investigated using the self-consistent field theory (SCFT) in conjunction with the string method. Usually, defect removal in two-dimensional hexagonal patterns involves reorganizing the cylindrical domains. Unlike atoms in solid crystals, the self-assembled cylindrical domains of block copolymers are "soft". Thus, the kinetic motions of the cylindrical domains resemble liquid droplets. Dislocations in hexagonal patterns are eliminated via creating and removing cylindrical domains. Our results show that new cylindrical domains are created via either a nucleation-like process or a fission-like process, whereas excessive domains are eliminated via a fusion-like or evaporation-like process. For weakly segregated block copolymers, the nucleation-like and evaporation-like processes are preferred.